This is going to be quite wordy, so bear with me.
The s25 plus and ultra support 2 charge modes. 10v 4.5a and 15v 3a. The s24 series only supported 10v.
Now, a usb cable is either normal or rated for 5a. To charge a phone at the full speed, you use a 5a cable, causing the phone to charge at 10v 4.5a 45w.
With the s25 series, you can use a normal non 5a cable, the phone will then swap to 15v 3a mode. Charging at 45w but with less amps.
With that said, there is an issue with this system. For me personally, the 15v 3a mode never enables. I have to use a 5a rated cable to charge at 45w. This can be checked as 45w says super fast charging 2.0. Otherwise it says super fast charging (no 2.0). My charger isn't by samsung but it supports everything required for these things to work correctly.
Meaning if I don't have a large 5a cable, I cannot charge at 45w, a feature the s25 series should have.
You'd expect this to be a single device issue a shop can fix. Many other people have reported the exact same issue. Samsung italy officially said they knew there was an issue but the other way round. They found issues with devices using 5a cables and says not to use them till the issue is fixed.
To to sum things up. The s25 series can charge at 45w with a non 5a cable. But for me and many other people, this is not possible and a 5a cable is required.
An official charger shouldn't be required as this whole thing uses an open standard. But I'm not buying a second charger to test it.
Kinda curious how it works with others. Get your 45w charger, charge using a normal thin cable, than a 5a cable. Does the phone say super fast charging 2.0 both times and which charger are you using?
The cable that came with your phone is a non 5a cable